Log Number: I7
Abstract Submitted to the    NANOTUBE'04 Conference:

Nanotubes in B-C-N and other selected inorganic systems as prospective functional materials

D. Golberg, Y. Bando, Y. Li, J. Hu, Y. Zhu, C. Tang

Advanced Materials Laboratory, National Institite for Materials Science, Tsukuba, Japan
Contact e-mail: golberg.dmitri@nims.go.jp

Nanotubes made of Boron Nitride and Boron-Carbon-Nitride were prepared and their electrical behavior, i.e. transport and field emission properties, were analyzed as a function of BN-rich and C-rich layer spatial arrangement and tube overall chemical composition. The I-V curves were measured in transmission and low energy electron point source microscopes. It was found that B-C-N nanotube conductance may be smoothly tuned as a function of these easy-to-control parameters. Inorganic nanotube (BN, MgO, C, In2O3, SiO2) filling with various materials, e.g. wide liquid range metals, oxygen-release compounds, semiconducting and ferromagnetic nanowires, was accomplished. This correspondingly creates: nanodevices for temperature measurements on a sub-micron scale; nanoscale oxygen burners/generators; and insulating nanocables for nanotechnology multi-purposes. Phase transformations, thermal expansion and crystallography of various filled phases confined with a nanotube shape were thor oughly investigated using HRTEM and electron diffraction with a nanosize electron probe. Semiconducting nanotubes made of widely used cubic lattice materials, i.e. GaN and Si were synthesized using templating. Finally, microtubes composed of C or Si were prepared. The latter tubes create new opportunities in performing in-channel nanotube metallurgical and chemical operations.

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