NANOTUBE'04 Conference:
Single-Walled Carbon Nanotubes by Microwave Plasma-Chemical Vapor Deposition
M. Maschmann, Amit. Goyal, Zafar. Iqbal, Tim Fisher, Roy Gat
FOr the first time Single-walled carbon nanotubes (SWCNTs) were grown by microwave plasma-enhanced chemical vapor deposition (PECVD). The substrate temperature was 800 oC. The gas mixture was methane and hydrogen. The catalysts was bimetallic Mo/Co supported on MgO and dispersed on a silicon wafer.
The nanotubes grew in bundles, each comprising of 5 to 10 individual single walled tubes with diameter distribution sharply peaked at 0.9 and 1.3nm. Raman analysis indicated the presence of both metallic and semiconducting tubes. Field-effect scanning electron microscopy and atomic force microscopy show that the bundles are approximately 5 to 10 nm in diameter and up to a few micrometers in length.
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