NANOTUBE'04 Conference:
Light-Assisted Oxidation for Selective Removal and Remaining of Single-Wall Carbon Nanotubes
M. Yudasaka, M. Zhang, Y. Miyauchi, S. Maruyama, S. Iijima
We previously reported that irradiation of light on SWNTs during the oxidation has an effect of enhancing the oxidation-disappearing of SWNTs [1]. It was also found that the diameters of the disappearing SWNTs were predicted from the wavelength of the irradiated light by using the Kataura-plot, which, in turn, was useful to make SWNTs with certain diameters to remain. These results indicate that the light-assisted oxidation would be a basic technique for photo-engineering of SWNTs. We also clarified the chiral index of oxidation-disappearing or remaining SWNTs with supporting information from optical absorption-spectrum, however, the chiral index thus clarified did not coincide with those determined by the fluorescence spectra. In addition to this, we noticed several unusual phenomena, a part of which are supposed to be caused by the SWNT bundling or surfactant-SWNT interaction. The details will be presented in the talk.
[1] Yudasaka et al. Chem. Phys. Lett. 374(2003)132.
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